With
the rapid development of EDM (Electrical Discharge Machining) industry, it has
higher and higher requirements for the used electrode. Both tungsten copper
with high content of W (mass fraction of W reaches 50%-90%) and tungsten copper with high content of
Cu (mass fraction of W reaches 50%-90%),
the most widely used are mixing method and infiltration method. Theoretically, the
mixing method has simple operations and can fabricate tungsten copper products
with any ratio of W and Cu. But the powder grain of raw material by this kind
of conventional process is too large and the density distribution is uneven, which
is difficult to fabricate tungsten copper electrode with compact structure
after pressing and sintering process.
While the infiltration process is suitable to fabricate tungsten
copper with 8%-40% content of Cu, tungsten skeleton infiltrated by copper in
molten state to obtain the densification. Although the infiltration process is
the most widely used in tungsten copper electrode now and it has stable working
properties, it also has some problems, such as many controlling parameters,
difficulties in porosity controlling, difficulties in porosity distribution and
so on. So the relevant scholars and researches have further explosion
surrounding the raw material preparation and molding process in recent years. Some
new technology has gradually developed, which is more practical and operational
effects are:
1. Pre-alloying: Its powder refinement
and even micro-alloying, so as to achieve increased activity and split the
purpose of promoting densification by mechanical and high energy ball milling;
2. Ultrafine particle / nano powder: By the addition of grain
growth inhibitors, high-energy ball milling, adding elements and changing the
material of the powder form and other methods to refine, even to the nanometer
level;
3. Thermoforming: it is pre-loaded with a good blend
in the mold cavity, rapid molding under heat and pressure to achieve
integration and briquettes pressed sintered compact so as to achieve the densification
effect;
4. Injection molding: the process is suitable for the manufacturing
of parts with complex structure and a smaller volume, which
prepared a uniform structure, precise size, but the control of process
parameters is more complex, and higher production cost of the mold;
5. Coated powder process: based on Cu cladded by W powder, which
will be an oxide, a compound or compound solution both doped together, dried
calcined powder coated after the reduction.
In addition, vacuum sintering, microwave
sintering, activated sintering, plasma arc welding sintering process all have
own advantages and application scope. Here we mainly introduce the coated
powder process by thermal chemical method.
没有评论:
发表评论